Premium
CH 3 SF 4 + SbF 6 − , a “Sulfuranonium” Salt
Author(s) -
Kleemann Gert,
Seppelt Konrad
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198110371
Subject(s) - salt (chemistry) , chemistry , nuclear chemistry
Methyl‐ and ethylsulfur pentafluoride readily react at low temperatures with AsF 5 or SbF 5 . An NMR spectroscopic investigation of the system H 3 CSbF 5 /SbF 5 , in SO 2 showed that primarily the title compound is formed at −70°C; it rapidly decomposes on heating. H 3 CSF 4 + SbF 6 −and H 5 C 2 SF 4 + SbF 6 −could find use as strong alkylating agents.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom