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Electrophilic Addition of a Sulfur, Selenium, and Tellurium Atom as well as of an SO 2 Molecule to a Metal‐Metal Bond
Author(s) -
Hofmann Werner,
Werner Helmut
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198110142
Subject(s) - sulfur , selenium , protonation , tellurium , chemistry , metal , atom (system on chip) , molecule , electrophile , cobalt , electrophilic addition , inorganic chemistry , photochemistry , organic chemistry , catalysis , ion , computer science , embedded system
The cobalt compound (1) reacts with elements of main group 6 and with SO 2 to give bridged complexes, e.g. the dinuclear complex (2) , which can be protonated or methylated an the sulfur atom.