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Gd 5 Cl 9 C 2 : A Structure with Two Condensed Metal Octahedral and Interstitial C 2 Groups
Author(s) -
Simon Arndt,
Warkentin Eberhard,
Masse René
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198110131
Subject(s) - octahedron , cluster (spacecraft) , crystallography , gadolinium , lanthanide , metal , chemistry , group (periodic table) , enhanced data rates for gsm evolution , crystal structure , materials science , ion , organic chemistry , telecommunications , computer science , programming language
The structure of the gadolinium compound Gd 5 Cl 9 C 2 is surprising in two respects: On the one hand, a novel cluster consisting of two edge‐to‐edge coupled metal octahedra is present, on the other, this is the first lanthanoid cluster compound in which the octahedral centers are occupied—namely, by C 2 ‐groups.