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Valence Isomerization of a cis ‐Diazene‐/Isodiazene‐ N ‐Oxide: Thermolysis of 7,8‐Diazabicyclo[4.2.2]deca‐2,4,7‐triene N ‐Oxide
Author(s) -
Olsen Henrik
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198109841
Subject(s) - isomerization , diradical , thermal decomposition , oxide , valence (chemistry) , chemistry , photochemistry , medicinal chemistry , organic chemistry , physics , catalysis , quantum mechanics , singlet state , excited state
The first example of the title reaction is the rearrangement ( 1 )→( 2 ), which most likely proceeds via the diradical ( 3 ).