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Palladation of sp 3 ‐Carbon Atoms: Preparation of N ‐PalladiomethyIthioamides
Author(s) -
Tamaru Yoshinao,
Kagotani Masahiro,
Yoshida Zenichi
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198109801
Subject(s) - carbon atom , nitrogen atom , carbon fibers , nitrogen , atom (system on chip) , chemistry , product (mathematics) , group (periodic table) , materials science , organic chemistry , ring (chemistry) , mathematics , computer science , geometry , composite number , composite material , embedded system
N,N ‐Dialkylthioamides can be regioselectively metalated with PdCl 2 ; thus, reaction of ( 2 ) with PdCl 2 in CH 3 OH leads to the orthometalated compound ( 1 ), while in HMPA the product of palladation contains a CH 2 group adjacent to the nitrogen atom.