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Synthesis of Dithiophosphinato Complexes with Bis(diorganothiophilosphoryl)disulfanes: Mo 3 S 7 ‐Cluster Dithiophosphinates
Author(s) -
Keck Helmut,
Kuclhen Wilhelm,
Mathow Jürgen,
Meyer Beate,
Mootz Dietrich,
Wunderlich Hartmut
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198109751
Subject(s) - cluster (spacecraft) , crystallography , physics , chemistry , computer science , operating system
Molybdenum‐sulfur clusters are of topical interest as model substances in bio‐inorganic chemistry. The readily soluble Mo 3 S 7 ‐cluster chelates ( 1 ) and ( 2 ) have been synthesized for the first time from Mo(CO) 6 and R 2 P(S)–S 2 –P(S)R 2 , R= Et or nPr. An X‐ray structure analysis of ( 1 ), a 1 :1 electrolyte, has been carried out. Further functionalization via suitable sub‐stituents R would seem to be possible.