Synthesis of Dithiophosphinato Complexes with Bis(diorganothiophilosphoryl)disulfanes: Mo 3 S 7 ‐Cluster Dithiophosphinates | Zendy

Keck Helmut | Zendy; Kuclhen Wilhelm | Zendy; Mathow Jürgen | Zendy; Meyer Beate | Zendy; Mootz Dietrich | Zendy; Wunderlich Hartmut | Zendy

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Synthesis of Dithiophosphinato Complexes with Bis(diorganothiophilosphoryl)disulfanes: Mo 3 S 7 ‐Cluster Dithiophosphinates

Author(s) -

Keck Helmut,

Kuclhen Wilhelm,

Mathow Jürgen,

Meyer Beate,

Mootz Dietrich,

Wunderlich Hartmut

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198109751

Subject(s) - cluster (spacecraft) , crystallography , physics , chemistry , computer science , operating system

Molybdenum‐sulfur clusters are of topical interest as model substances in bio‐inorganic chemistry. The readily soluble Mo 3 S 7 ‐cluster chelates ( 1 ) and ( 2 ) have been synthesized for the first time from Mo(CO) 6 and R 2 P(S)–S 2 –P(S)R 2 , R= Et or nPr. An X‐ray structure analysis of ( 1 ), a 1 :1 electrolyte, has been carried out. Further functionalization via suitable sub‐stituents R would seem to be possible.

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