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Synthesis and Structure of a Non‐Polymeric Molecule Containing Eleven Alternating Sulfur‐ and Nitrogen‐Atoms
Author(s) -
Witt Michael,
Roesky Herbert W.,
Noltemeyer Mathias,
Clegg William,
Schmidt Martin,
Sheldrick George M.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198109741
Subject(s) - sulfur , nitrogen , molecule , chemistry , cleavage (geology) , orange (colour) , polymer chemistry , stereochemistry , organic chemistry , materials science , food science , fracture (geology) , composite material
In compound ( 2 ), which formally stands between (SN) x and the sulfur imides , the average SN bond length is 1.602 Å and is thus similar to that in (SN) x (1.611 Å). ( 2 ) is formed as orange needles from the blood‐red ( 1 ) in acetoni‐trile by cleavage of S 4 N 4 and sulfur.