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[Ga 6 Se 14 ] 10− : A 1900 pm Long, Hexameric Anion
Author(s) -
Deiseroth HansJörg,
FuSon Han
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198109621
Subject(s) - crystallography , ion , ternary operation , tetrahedron , chemistry , materials science , organic chemistry , computer science , programming language
The first ternary compound in the Cs/Ga/Se system, whose structure was investigated on single crystals , is a solid of the composition Cs 10 Ga 6 Se 14 . The pale‐yellow, transparent, leaf‐shaped crystals contain the anion [Ga 6 Se 14 ] 10− ( 1 ), which is composed of six linearly edge‐linked GaSe 4 tetrahedra.