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A New Cationic Hydrido‐Bridged Rhodium( I )‐Iridium( III ) Complex
Author(s) -
Albinati Alberto,
Musco Alfredo,
Naegeli Ralph,
Venanzi Luigi M.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198109581
Subject(s) - rhodium , cationic polymerization , iridium , chemistry , hydride , stereochemistry , catalysis , medicinal chemistry , polymer chemistry , organic chemistry , hydrogen
The new complex ( 1 ), whose dark green crystals are stable in air, contains a five‐coordinate rhodium( I ) and a six‐coordinate irid‐ium( III ) with three bridging hydride ligands. ( 1 ) can be prepared by reaction of [Rh(di‐phos)(MeOH) 2 ][BF 4 ] with mer ‐[IrH 3 (PEt 3 ) 3 ] and subsequent precipitation with NaBPh 4 .