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Complexes of Iridium with Terminal PF 2 ‐Ligands
Author(s) -
Ebsworth E. A. V.,
McManus Neil T.,
Rankin David W. H.,
Whitelock John D.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198108011
Subject(s) - iridium , terminal (telecommunication) , chemistry , metal , crystallography , stereochemistry , polymer chemistry , organic chemistry , catalysis , computer science , telecommunications
Unusual structures with metal‐bonded tricoordinate phosphorus are involved in the stable iridium compounds of type B (X = Q = Cl, Br, I); they are formed from complexes of type A—prepared at −40°C from PF 2 X and trans ‐Ir(CO)X(PEt 3 ) 2 —by rearrangement at room temperature.
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