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Synthesis of Hydrido(phenyl)osmium( II )‐ from Benzeneosmium(0)‐Complexes: Intramolecular Insertion of a Lewis Basic Metal Atom into an sp 2 ‐CH Bond [1]
Author(s) -
Werner Rainer,
Werner Helmut
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198107931
Subject(s) - osmium , intramolecular force , chemistry , benzene , metal , lewis acids and bases , medicinal chemistry , benzoic acid , atom (system on chip) , propene , catalysis , stereochemistry , insertion reaction , crystallography , ruthenium , organic chemistry , computer science , embedded system
The intramolecular insertion of osmium(0) into a CH bond of complexed benzene proceeds via formation of the C 6 H 5 Os II H partial structure. This result can be considered as a step on the route to a metal‐catalyzed synthesis of e.g. benzoic acid from benzene and CO 2 . The reaction (1) → (2) was also performed with (1) , using propene instead of ethene.