Synthesis of Hydrido(phenyl)osmium( II )‐ from Benzeneosmium(0)‐Complexes: Intramolecular Insertion of a Lewis Basic Metal Atom into an sp 2 ‐CH Bond [1] | Zendy

Werner Rainer | Zendy; Werner Helmut | Zendy

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Synthesis of Hydrido(phenyl)osmium( II )‐ from Benzeneosmium(0)‐Complexes: Intramolecular Insertion of a Lewis Basic Metal Atom into an sp 2 ‐CH Bond [1]

Author(s) -

Werner Rainer,

Werner Helmut

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198107931

Subject(s) - osmium , intramolecular force , chemistry , benzene , metal , lewis acids and bases , medicinal chemistry , benzoic acid , atom (system on chip) , propene , catalysis , stereochemistry , insertion reaction , crystallography , ruthenium , organic chemistry , computer science , embedded system

The intramolecular insertion of osmium(0) into a CH bond of complexed benzene proceeds via formation of the C 6 H 5 Os II H partial structure. This result can be considered as a step on the route to a metal‐catalyzed synthesis of e.g. benzoic acid from benzene and CO 2 . The reaction (1) → (2) was also performed with (1) , using propene instead of ethene.

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