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Thiaphosphametallacyclopentadienes as Intermediates in the Cyclotrimerization of Alkynes with their Phosphorus‐Sulfur Analogues
Author(s) -
Lindner Ekkehard,
Rau Axel,
Hoehne Sigurd
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198107871
Subject(s) - sulfur , phosphorus , chemistry , combinatorial chemistry , medicinal chemistry , organic chemistry
Similar intermediates as in the metal catalyzed cyclotrimerization of alkynes can be trapped in the presence of their phosphorus‐sulfur analogues: the metallacyclopentadiene (1) and the bicycle (2) with the partial structure.