Determination of the Absolute Configuration of Alkyl(phenyl)thiophosphinic  O ‐Acids and of  O ‐Alkyl Alkylthiophosphonates from the Circular Dichroism of Their Complexes with [Mo 2 (O 2 CCH 3 ) 4 ] | Zendy

Omelańczuk Jan | Zendy; Snatzke Günther | Zendy

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Determination of the Absolute Configuration of Alkyl(phenyl)thiophosphinic O ‐Acids and of O ‐Alkyl Alkylthiophosphonates from the Circular Dichroism of Their Complexes with [Mo 2 (O 2 CCH 3 ) 4 ]

Author(s) -

Omelańczuk Jan,

Snatzke Günther

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198107861

Subject(s) - alkyl , circular dichroism , absolute configuration , pyridine , solvent , chemistry , crystallography , wavelength , stereochemistry , medicinal chemistry , materials science , organic chemistry , optoelectronics

The absolute configuration of the phosphorus compounds (2) and (3) can be determined from the circular dichroism of their in situ complexes with the dimolybdenum compound (1) . The solvent is CF 3 CO 2 H or pyridine. In direct CD measurements—without (1) —the Cotton effect lies in a difficultly accessible wavelength region.

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