Dispiro[2.0.2.4]deca‐7,9‐diene as a Ligand in Carbonyl‐Transition Metal Complexes | Zendy

Wormsbächer Dieter | Zendy; Edelmann Frank | Zendy; Kaufmann Dieter | Zendy; Behrens Ulrich | Zendy; de Meijere Armin | Zendy

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Dispiro[2.0.2.4]deca‐7,9‐diene as a Ligand in Carbonyl‐Transition Metal Complexes

Author(s) -

Wormsbächer Dieter,

Edelmann Frank,

Kaufmann Dieter,

Behrens Ulrich,

de Meijere Armin

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198106961

Subject(s) - moiety , diene , chemistry , derivative (finance) , ligand (biochemistry) , ring (chemistry) , transition metal , medicinal chemistry , deca , stereochemistry , organic chemistry , catalysis , receptor , biochemistry , natural rubber , financial economics , economics

No opening of the three‐membered ring takes place on reaction of a cyclohexadiene derivative containing a spirobicyclopropyl moiety with carbonyliron complexes. The stable cation‐complex (1) . X = BF 4 , can be synthesized by reaction of tricarbonyl(cyclohexadienyl)iron with HBF 4 .

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