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Gas Chromatographic Separation of Carbohydrate Enantiomers on a New Chiral Stationary Phase
Author(s) -
König Wilfried A.,
Benecke Ingrid,
Bretting Hagen
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198106931
Subject(s) - enantiomer , chromatography , helix pomatia , chemistry , chiral stationary phase , stationary phase , capillary electrochromatography , phase (matter) , carbohydrate , capillary gas chromatography , gas chromatography , organic chemistry , snail , ecology , biology
The direct separation of simple, volatile derivatives of enantiomeric sugars has been achieved for the first time by glass‐capillary gas chromatography of trifluoroacetyl derivatives on a temperature‐stable, chiral stationary phase. The usefulness of the new method was demonstrated on an hydrolyzate of the galactan of the snail Helix pomatia.