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Synthesis of α‐Trimethylsiloxythiolene and α,α′‐Bis(trimethylsiloxy) Disulfides
Author(s) -
Aida T.,
Chan T.H.,
Harpp David N.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198106911
Subject(s) - pyridine , chemistry , organic chemistry , polymer chemistry
α‐Trimethylsiloxythiols (1) have been synthesized in good yields for the first time –from aldehydes, H 2 S and (CH 3 ) 3 SiCl in the presence of pyridine. The disulfides (2) were also obtained in good yields, by oxidation of (1) with MnO 2 . The thiols (1) can be added to olefins photochemically.
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