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Synthesis of a Novel Amphoteric Polyelectrolyte by Polymerization of 6‐Amino‐2,4‐hexadienoic Acid in Layer Perovskites
Author(s) -
Tieke Bernd,
Wegner Gerhard
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198106871
Subject(s) - polyelectrolyte , polymerization , monomer , polymer , polymer chemistry , reactivity (psychology) , tacticity , chemistry , materials science , chemical engineering , organic chemistry , medicine , pathology , engineering , alternative medicine
The topochemically controlled polymerization of 6‐amino‐2,4‐hexadienoic acid in complexes with CdCl 2 , MnCl 2 and FeCl 2 is initiated by UV or 60 Co‐γ‐radiation. Tacticity of the polymer, slight structural changes during transition from the monomer to polymer and control of reactivity by the type of ion in the matrix render the proposed course of reaction likely. The liberated amphoteric polyelectrolyte could be suitable as a polymeric complexing agent.