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Cluster‐Construction: Synthesis and Structure of Fe 2 Co 2 (CO) 11 (PC 6 H 5 ) 2 and Fe 2 Co 2 (CO) 11 S 2
Author(s) -
Vahrenkamp Heinrich,
Wucherer Edward J.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198106801
Subject(s) - cluster (spacecraft) , crystallography , physics , chemistry , materials science , computer science , operating system
A synthetic concept for the construction of tetranuclear clusters from two dinu‐clear clusters exploits for the first time the finding that clusters are stabilized by ligand bridging [ (la) , E′ = PPhH, (1b) . E′ = S (with SS bonding); (2a) , E = PPh, (2b) , E = S].
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