Premium
Valence Isomerization of an Imino(methylene)phosphorane to a 1,2λ 3 ‐Azaphosphiridine: A Novel Rearrangement in the Phosphorus System
Author(s) -
Niecke Edgar,
Seyer Anette,
Wildbredt DirkAndreas
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198106751
Subject(s) - phosphorane , chemistry , isomerization , methylene , alkyl , valence (chemistry) , medicinal chemistry , ring (chemistry) , silylation , stereochemistry , organic chemistry , catalysis
The thermal rearrangement of the N ‐alkyl‐ated amino(imino)phosphorane (1) into the three‐membered ring (2) is a surprising reaction, for N‐silylated analogues of (1) form diiminophosphoranes by 1,3‐shift of a silyl group. (R = i Pr, R′ = t Bu)
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom