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New Tungsten‐Iridium Dinuclear Complexes Containing Cyclopentadienyl and Hydrido Bridges
Author(s) -
Pregosin Paul S.,
Togni Antonio,
Venanzi Luigi M.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198106682
Subject(s) - iridium , cyclopentadienyl complex , tungsten , chemistry , tungsten compounds , crystallography , catalysis , organic chemistry
The green, air‐stable tungsten‐iridium dinu‐clear complex ( 1 ), L = PEt 3 , is the first species known to contain C 5 H 4 2−and H − together as bridging ligands. Its structure is secured by NMR data.