Synthesis of a Novel Biscarbene Type of Complex [1] | Zendy

Fischer Ernst Otto | Zendy; Röll Werner | Zendy; Schubert Ulrich | Zendy; Ackermann Klaus | Zendy

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Synthesis of a Novel Biscarbene Type of Complex [1]

Author(s) -

Fischer Ernst Otto,

Röll Werner,

Schubert Ulrich,

Ackermann Klaus

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198106111

Subject(s) - tungsten , molybdenum , octahedron , alkylation , chelation , colored , chemistry , crystallography , type (biology) , permanganate , inorganic chemistry , materials science , crystal structure , organic chemistry , geology , catalysis , paleontology , composite material

o ‐Dilithiobenzene adds hexacarbonylchromium, ‐molybdenum or tungsten; alkylation of the intermediates leads to the 1,4‐chelated biscarbene complexes (1) – (3) , which are stable as permanganate‐colored to black leaflets at room temperature. Spectroscopic studies show that these compounds have a distorted octahedral structure.

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