Premium
Silaethene
Author(s) -
Maier Günther,
Mihm Gerhard,
Reisenauer Hans Peter
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198105971
Subject(s) - argon , cleavage (geology) , infrared spectroscopy , crystallography , chemistry , matrix (chemical analysis) , physics , materials science , atomic physics , organic chemistry , composite material , fracture (geology) , chromatography
H 2 SiCH 2 , the simplest compound with SiC double bonding was generated by retrodiene cleavage from the bicycle (1) , X = H, isolated in an argon matrix at 10 K, and identified by IR and UV spectra. On warming, (2) (X = H) is formed. Derivatives with X = D and X = Cl behave analogously.
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