Premium
Stereoselective Cyclopropane Syntheses by “Oxy‐Homodienyl Hydrogen Shifts”
Author(s) -
Klärner FrankGerrit,
Rüngeler Wolfgang,
Maifeld Werner
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198105951
Subject(s) - cyclopropane , stereoselectivity , chemistry , diene , hydrogen , stereochemistry , computational chemistry , medicinal chemistry , organic chemistry , catalysis , ring (chemistry) , natural rubber
The stereoselective rearrangement of hexadienols (1) into cyclopropylacetaldehydes (2) , R 4 = H, or cyclopropylmethyl methyl ketones (2) , R 4 = CH 3 , takes place by “oxy‐homodienyl hydrogen shift”. In the case of the corresponding hydrocarbons the equilibrium is on the side of the acyclic diene.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom