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Coordination of Dimethyl(thionitroso)amine to Pentacarbonylchromium via the Sulfur Atom
Author(s) -
Roesky Herbert W.,
Emmert Ralf,
Clegg William,
Isenberg Wilhelm,
Sheldrick George M.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198105912
Subject(s) - sulfur , amine gas treating , chemistry , atom (system on chip) , medicinal chemistry , organic chemistry , computer science , operating system
Unstable (1) , coordinated to the metal via sulfur and not via nitrogen is the first acyclic sulfur‐nitrogen ligand. The 1:1 complex (2) forms stable ruby‐red crystals at room temperature.