Premium
A Diorganotin Oxide with a Planar Tin‐Chalcogen Six‐Membered Ring
Author(s) -
Puff Heinrich,
Schuh Willi,
Sievers Rolf,
Zimmer René
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198105911
Subject(s) - chalcogen , ring (chemistry) , toluene , tin , boiling , planar , oxide , chemistry , solid state , tin oxide , inorganic chemistry , materials science , organic chemistry , polymer chemistry , computer graphics (images) , computer science
The first compound containing a planar (SnO) 3 ‐ring is a form of (1) readily soluble in organic solvents, even in the cold; (1) was obtained on reaction of t Bu 2 SnCl 2 with NaOH in boiling toluene. So far only sparingly soluble (1) –probably polymeric in the solid state–was known.