Redox Reltionship between Carbeneiron and σ‐Alkyliron Porphyrins | Zendy

Lexa Doris | Zendy; Savéant JeanMichel | Zendy; Battioni JeanPaul | Zendy; Lange Marc | Zendy; Mansuy Daniel | Zendy

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Redox Reltionship between Carbeneiron and σ‐Alkyliron Porphyrins

Author(s) -

Lexa Doris,

Savéant JeanMichel,

Battioni JeanPaul,

Lange Marc,

Mansuy Daniel

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198105781

Subject(s) - redox , chemistry , reduction (mathematics) , porphyrin , medicinal chemistry , oxidation reduction , stereochemistry , combinatorial chemistry , photochemistry , inorganic chemistry , biochemistry , geometry , mathematics

σ‐Alkyliron porphyrins, both with Fe II as well as with Fe III can be generated from carbeneiron ( II ) porphyrins by cyclovoltammetric reduction. (TPP) Fe(HCCPh 2 )—a σ‐vinyl‐Fe II complex–was also independently synthesized from (TPP)Fe(ClO 4 ) and BrMgCHCPh 2 ; its properties resemble those of the product of the (2e + H ⊕ )‐reduction of (TPP) Fe(:CCPh 2 ).

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