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Synthesis of (±)‐13‐Deoxo‐11‐deoxydaunorubicinone
Author(s) -
Krohn Karsten
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198105761
Subject(s) - yield (engineering) , combinatorial chemistry , anthraquinone , key (lock) , stereochemistry , chemistry , computer science , organic chemistry , physics , computer security , thermodynamics
The naturally occurring title compound (2) , an interesting antibiotic , has been synthesized for the first time. The key step was cyclization of the 2,3‐dialkylated anthraquinone (1) , which proceeded in 70 % yield.