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Mo IV in Aqueous Solutions: The Trinuclear Cluster [Mo IV O 4 F 9 ] 5− , the First Species Isolated from Mineral Acid Solution
Author(s) -
Müller Achim,
Ruck Andreas,
Dartmann Mechthild,
ReinschVogell Uta
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198104831
Subject(s) - aqueous solution , cluster (spacecraft) , chemistry , inorganic chemistry , nuclear chemistry , programming language , computer science
What species are present in acid, aqueous, Mo IV ‐containing solutions? This long discussed question has now been answered in one case: In the presence of HF and NH 4 F the species (NH 4 ) 5 [Mo 3 O 4 F 9 ]·NH 4 F·H 2 O could be isolated.