Stable Metal‐Phthalocyanines as Poison‐Resistant Catalysts in Homogeneous Catalysis: Reduction of Organic Compounds with NaBH 4 | Zendy

Eckert Heiner | Zendy; Kiesel Yvonne | Zendy

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Stable Metal‐Phthalocyanines as Poison‐Resistant Catalysts in Homogeneous Catalysis: Reduction of Organic Compounds with NaBH 4

Author(s) -

Eckert Heiner,

Kiesel Yvonne

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198104731

Subject(s) - catalysis , homogeneous , phthalocyanine , metal , reducing agent , reduction (mathematics) , chemistry , inorganic chemistry , materials science , combinatorial chemistry , organic chemistry , physics , geometry , mathematics , thermodynamics

The metal phthalocyanines MPc (M = VO, Mn, Fe, Co, Pd) related to vitamin B 12 are stable reduction catalysts having advantageous properties and also potential industrial applications. These compounds are soluble (MPc ⊖ ) during the reduction (with NaBH 4 ) and insoluble (MPc) under non‐reducing conditions. They enable selective reductions and are not, or rarely, poisoned by SH ⊖ , CN ⊖ , or I ⊖ .

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