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A Triple‐Decked Sandwich Complex of Rhodium with 1,4‐Diborabenzene as Bridging Ligand
Author(s) -
Herberich Gerhard E.,
Hessner Bernd,
Huttner Gottfried,
Zsolnai Laszlo
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198104721
Subject(s) - bridging (networking) , rhodium , valence (chemistry) , crystallography , transition metal , polyhedron , hexagonal crystal system , ligand (biochemistry) , bridging ligand , metal , materials science , chemistry , stereochemistry , crystal structure , geometry , mathematics , metallurgy , computer science , catalysis , organic chemistry , receptor , computer network , biochemistry
The first sandwich complex with a six‐membered bridging ligand , namely the cation (1) , was obtained from the corresponding mono‐nuclear sandwich complex in CF 3 COOH. The 30‐valence electron complex (1) is at the same time the first triple‐decked complex containing a heavy transition metal. It has a hexagonal‐pyramidal structure previously not observed in 8‐cornered closo ‐polyhedra.