A Triple‐Decked Sandwich Complex of Rhodium with 1,4‐Diborabenzene as Bridging Ligand | Zendy

Herberich Gerhard E. | Zendy; Hessner Bernd | Zendy; Huttner Gottfried | Zendy; Zsolnai Laszlo | Zendy

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A Triple‐Decked Sandwich Complex of Rhodium with 1,4‐Diborabenzene as Bridging Ligand

Author(s) -

Herberich Gerhard E.,

Hessner Bernd,

Huttner Gottfried,

Zsolnai Laszlo

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198104721

Subject(s) - bridging (networking) , rhodium , valence (chemistry) , crystallography , transition metal , polyhedron , hexagonal crystal system , ligand (biochemistry) , bridging ligand , metal , materials science , chemistry , stereochemistry , crystal structure , geometry , mathematics , metallurgy , computer science , catalysis , organic chemistry , receptor , computer network , biochemistry

The first sandwich complex with a six‐membered bridging ligand , namely the cation (1) , was obtained from the corresponding mono‐nuclear sandwich complex in CF 3 COOH. The 30‐valence electron complex (1) is at the same time the first triple‐decked complex containing a heavy transition metal. It has a hexagonal‐pyramidal structure previously not observed in 8‐cornered closo ‐polyhedra.

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