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Ca 3 AlAs 3 —An Intermetallic Analogue of the Chain Silicates
Author(s) -
Cordier Gerhard,
Schäfer Herbert
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198104661
Subject(s) - intermetallic , tetrahedron , crystallography , materials science , chain (unit) , inorganic chemistry , chemistry , metallurgy , physics , alloy , astronomy
Chains of AlAs 4 tetrahedra have been detected in the intermetallic compound Ca 3 AlAs 3 . Hence, it could be shown for the first time that such groups of chains also occur in Zintl phases—and not only in silicates and polyphosphates.