Crystal structure of 2‐Lithio‐2‐phenyl‐1,3‐dithiane‐Tetrahydrofuran‐Tetramethylethylenediamine (1/1/1); Electron‐Density Difference Maps for Lithio‐methyl‐ and Lithio‐phenyl‐dithiane | Zendy

Amstutz René | Zendy; Dunitz Jack D. | Zendy; Seebach Dieter | Zendy

Premium

Crystal structure of 2‐Lithio‐2‐phenyl‐1,3‐dithiane‐Tetrahydrofuran‐Tetramethylethylenediamine (1/1/1); Electron‐Density Difference Maps for Lithio‐methyl‐ and Lithio‐phenyl‐dithiane

Author(s) -

Amstutz René,

Dunitz Jack D.,

Seebach Dieter

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198104651

Subject(s) - dithiane , tetrahydrofuran , tetramethylethylenediamine , chemistry , crystal structure , crystallography , medicinal chemistry , organic chemistry , solvent

A non‐ionic and a contact ion pair LiC bond have been detected in complexed 2‐methyl‐ (1) and 2‐phenyl‐2‐lithio‐1,3‐dithiane (2) , respectively. This was achieved by determination of bond electron densities from the X‐ray diffraction data of single crystals of the two compounds.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research