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Insertion of —CN into the Metal‐Carbene Carbon Bond: A Route to Methyleneaminocarbene Complexes
Author(s) -
Fischer Helmut,
Schubert Ulrich
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198104611
Subject(s) - carbene , moiety , ligand (biochemistry) , chemistry , metal , molecule , transition metal carbene complex , carbon fibers , stereochemistry , crystallography , polymer chemistry , materials science , organic chemistry , catalysis , biochemistry , receptor , composite number , composite material
Novel, readily accessible carbene complexes (1) containing thecarbene structural moiety are characterized by their mode of formation (attack of the entering molecule at the ligand) and the unusual n π —p π bond between C carbene and NMe 2 .
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