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Photochemical Synthesis of Bis(η 2 ‐methyl acrylate)tricarbonylruthenium
Author(s) -
Grevels FriedrichWilhelm,
Reuvers Johannes G. A.,
Takats Josef
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198104521
Subject(s) - olefin fiber , acrylate , methyl acrylate , chemistry , irradiation , photochemistry , polymer chemistry , medicinal chemistry , organic chemistry , catalysis , copolymer , polymer , physics , nuclear physics
The first (η 2 ‐olefin) 2 Ru(CO) 3 complex , the title compound ( 1 ), was obtained by irradiation of Ru 3 (CO) 12 and methyl acrylate. The reaction proceeds via (η 2 ‐olefin)Ru(CO) 4 . Two fluxional systems of ( 1 )‐isomers are present in solution and can be differentiated by the arrangement of the olefin ligands.
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