Carbonylation of C 5 H 5 Fe(CO)(CH 3 )L— a CO‐Insertion and No CH 3 ‐Migration | Zendy

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Carbonylation of C 5 H 5 Fe(CO)(CH 3 )L— a CO‐Insertion and No CH 3 ‐Migration

Author(s) -

Brunner Henri,

Vogt Heinz

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198104051

Subject(s) - carbonylation , chemistry , stereospecificity , molecule , transition metal , metal , migratory insertion , stereochemistry , group (periodic table) , carbon monoxide , crystallography , medicinal chemistry , catalysis , organic chemistry

The reaction of organo‐transition metal compounds with CO has been investigated in the optically active iron complex (1) . Unlike CH 3 Mn(CO) 5 , the complex (1) is carbonylated with stereospecific insertion of the CO group present in the molecule into the Fe—CH 3 bond to give (2) . The η 2 ‐acetyl complex (3) (L = PPh 2 NMe—( S )‐CHMePh) is the most likely intermediate, also during de‐carbonylation.

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