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Axially Unsymmetrical Osmium( II )‐Porphyrins with Sulfur and Nitrogen Donors as Models for Cytochrome c Models
Author(s) -
Buchler Johann Walter,
Kokisch Wolfgang
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198104031
Subject(s) - tetrahydrothiophene , osmium , cytochrome c , chemistry , porphyrin , sulfur , ligand (biochemistry) , nitrogen , heme , cytochrome , axial symmetry , stereochemistry , medicinal chemistry , biochemistry , organic chemistry , catalysis , receptor , enzyme , mitochondrion , structural engineering , engineering , ruthenium
Cytochrome c with its NFeS group, and novel compounds (1) containing an NOS group show some remarkable similarities. A particularly promising ligand combination is L = 1‐methylimidazole, L′ = tetrahydrothiophene, which effects a “push‐pull” stabilization.