Axially Unsymmetrical Osmium( II )‐Porphyrins with Sulfur and Nitrogen Donors as Models for Cytochrome c Models | Zendy

Buchler Johann Walter | Zendy; Kokisch Wolfgang | Zendy

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Axially Unsymmetrical Osmium( II )‐Porphyrins with Sulfur and Nitrogen Donors as Models for Cytochrome c Models

Author(s) -

Buchler Johann Walter,

Kokisch Wolfgang

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198104031

Subject(s) - tetrahydrothiophene , osmium , cytochrome c , chemistry , porphyrin , sulfur , ligand (biochemistry) , nitrogen , heme , cytochrome , axial symmetry , stereochemistry , medicinal chemistry , biochemistry , organic chemistry , catalysis , receptor , enzyme , mitochondrion , structural engineering , engineering , ruthenium

Cytochrome c with its NFeS group, and novel compounds (1) containing an NOS group show some remarkable similarities. A particularly promising ligand combination is L = 1‐methylimidazole, L′ = tetrahydrothiophene, which effects a “push‐pull” stabilization.

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