A Novel Organometallic Cluster with Ir 4 C 2 ‐framework and Fluxional Hydrido Bridges | Zendy

Müller Jörn | Zendy; Menig Helmuth | Zendy; Pickardt Joachim | Zendy

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A Novel Organometallic Cluster with Ir 4 C 2 ‐framework and Fluxional Hydrido Bridges

Author(s) -

Müller Jörn,

Menig Helmuth,

Pickardt Joachim

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198104011

Subject(s) - cluster (spacecraft) , organometallic chemistry , group 2 organometallic chemistry , olefin fiber , chemistry , 1,5 cyclooctadiene , crystallography , stereochemistry , molecule , catalysis , organic chemistry , crystal structure , computer science , programming language

Several unusual features characterize the novel organometallic cluster (1) : fluxional hydrido bridges in solution, no CO‐ligands, only π‐bonded olefin ligands, stable up to ca . 230 °C, formation from [Ir(COD)Cl] 2 and i ‐C 3 H 7 MgBr (COD = cyclooctadiene), etc .

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