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A Novel Carbonyldiniobium Complex with Hydrogen Bridge
Author(s) -
Herrmann Wolfgang A.,
Biersack Helmut,
Ziegler Manfred L.,
Wülknitz Peter
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198103881
Subject(s) - bent molecular geometry , bridge (graph theory) , hydrogen , chemistry , crystallography , materials science , stereochemistry , organic chemistry , medicine
The first homodinuclear carbonyl compound , the hydrido complex (3) , was obtained in a light‐induced reaction from the newly accessible (1) and (2) . The (η 5 ‐C 5 H 5 ) 2 Nb(CO) 3 ‐ and (η 5 ‐C 5 H 5 )Nb(CO)‐fragments are coupled by a slightly bent H‐bridge.