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Photochemical Formation of and Ligand Exchange in a Cationic Dithiolatonickel Complex
Author(s) -
Vogler Arnd,
Kunkely Horst
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198103861
Subject(s) - cationic polymerization , ligand (biochemistry) , chemistry , photochemistry , complex formation , metal , transition metal , polymer chemistry , inorganic chemistry , organic chemistry , catalysis , receptor , biochemistry
The first cationic transition metal complex containing a 1,2‐dithiolato ligand , (1) , was generated photochemically from the neutral complex in chlorinated solvents. (1) is stable at low temperature; at room temperature an unusual ligand‐exchange takes place.