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Cobaltaheterocycles by [3+2]‐Cycloaddition of an Acetimidoylcobalt Complex with Acetone and Acetonitrile
Author(s) -
Werner Helmut,
Heiser Bernd,
Kühn Alfred
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198103001
Subject(s) - acetonitrile , acetone , cycloaddition , nucleophile , chemistry , medicinal chemistry , organic chemistry , catalysis
The high nucleophilicity of the acctimidoyl N‐itom in [C 5 H 5 Co(Pme 3 )Me(CNMe)]I enables [3+2]‐cycloadditions with acetone and acetonitrile, whose multiple bonds are only slightly activated. With acetonitrile, (1) is formed. The analogous acetimidoyl complex of rhodium forms no rhodaheterocycles.