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Biosynthesis of Natural Porphyrins: Studies with Isomeric Hydroxymethylbilanes on the Specificity and Action of Cosynthetase
Author(s) -
Battersby Alan R.,
Fookes Christopher J. R.,
Matcham George W. J.,
Pandey Pramod S.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198102931
Subject(s) - ring (chemistry) , stereochemistry , chemistry , biosynthesis , inversion (geology) , action (physics) , biochemistry , physics , biology , organic chemistry , gene , paleontology , quantum mechanics , structural basin
The Cosynthetase‐catalyzed cyclization (1) → (2) , which proceeds with “inversion” of ring D, does not start with rearrangement into the open‐chain isomer with inverted ring D.