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Intramolecular Nucleophilic Addition in a Thiolatobridged “Crown‐like” Iridium Complex
Author(s) -
Devillers Jean,
de Montauzon Dominique,
Poilblanc René
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198102872
Subject(s) - iridium , intramolecular force , chemistry , ring (chemistry) , nucleophile , atom (system on chip) , nucleophilic addition , alkane , crystallography , stereochemistry , organic chemistry , catalysis , computer science , embedded system
An iridium complex exhibiting several unusual properties , the title compound (2) , is formed on reaction of (1) with an excess of hexafluoro‐2‐butyne at −196 °C. X‐ray structure analysis confirms the six‐membered ring of three S‐, two Ir II ‐atoms and one Ir I ‐atom, the different bonding of the alkane ligands, and the coordination of a S atom.