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A Convenient Synthesis of “Homoazulene” (1,5‐Methano[10]annulene)
Author(s) -
Scott Lawrence T.,
Brunsvold William R.,
Kirms Mark A.,
Erden Ihsan
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198102741
Subject(s) - annulene , chemistry , computational chemistry , combinatorial chemistry
Our present understanding of cyclic conjugation in non‐benzenoid systems is based in part on investigations of bridged annulenes such as (1) and (2) . The new method presented here permitted the first synthesis of (1) in large amounts.