Trinuclear Clusters from HCo(CO) 4  Solutions | Zendy

Fachinetti Giuseppe | Zendy; Balocchi Laura | Zendy; Secco Fernando | Zendy; Venturini Marcella | Zendy

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Trinuclear Clusters from HCo(CO) 4 Solutions

Author(s) -

Fachinetti Giuseppe,

Balocchi Laura,

Secco Fernando,

Venturini Marcella

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198102041

Subject(s) - hydroformylation , cluster (spacecraft) , homogeneous , decomposition , thermal decomposition , catalysis , chemistry , rhodium , inorganic chemistry , physics , thermodynamics , organic chemistry , computer science , programming language

HCo 3 (CO) 9(3) is the first isolable hydrido‐carbonyl cluster , which can be obtained using HCo(CO) 4 (1) as starting compound. The trinuclear, electronically unsaturated cluster is formed by thermal decomposition of (1) together with the expected Co 2 (CO) 8 (2) . Lower nuclear clusters such as (3) are discussed as catalysts, e.g. in homogeneous hydroformylation or CO reduction.

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