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Lewis Acid Catalyzed Alkylations of CC‐Multiple Bonds; Rules for Selective Enlargements of Carbon Skeletons
Author(s) -
Mayr Herbert
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198101841
Subject(s) - cationic polymerization , electrophile , alkylation , chemistry , catalysis , lewis acids and bases , combinatorial chemistry , organic chemistry , product (mathematics) , polymer chemistry , geometry , mathematics
A preconception or many organic chemists, that cationic CC couplings are difficulty controllable and frequently lead to oligo‐ and polymeric products, would appear no longer to hold. If a difficultly ionizable product BX is formed from a readily ionizable educt AX in an electrophilic alkylation, then good yields can be achieved.