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Trimethylsilylmethyl Isothiocyanate, An Isothiocyanatomethanide Equivalent
Author(s) -
Hirao Toshikazu,
Yamada Atsushi,
Ohshiro Yoshiki,
Agawa Toshio
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198101261
Subject(s) - carbanion , tetrabutylammonium fluoride , chemistry , fluoride , catalysis , isothiocyanate , organic chemistry , medicinal chemistry , inorganic chemistry
Isothiocyanato carbanions of type (2) are suitable building blocks for use in heterocyclic syntheses . These species can be prepared from the title compound (1a) using catalytic amounts of tetrabutylammonium fluoride and reacts with carbonyl compounds to give oxazilidinethiones (3).