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η 3 ‐Allyl(hydrido)phosphaneplatinum( II ) Complexes
Author(s) -
Carturan Giovanni,
Scrivanti Alberto,
Morandini Franco
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198101121
Subject(s) - propene , olefin fiber , chemistry , medicinal chemistry , stereochemistry , catalysis , organic chemistry
The synthesis of the complex (1) , M = Pt, R = P( t Bu) 3 or P( c ‐C 6 H 11 ) 3 , is of interest in altering the position of equilibrium between allyl(hydrido) and olefin complexes, which could be a key step in selective hydrogenation reactions. The complexes (1) decompose above −30 °C with the formation of propene.