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(NH 4 ) 4 [P 4 S 8 ]·2H 2 O, the Salt of a “Square” Phosphoric Acid
Author(s) -
Falius Hans,
Krause Werner,
Sheldrick William S.
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198101031
Subject(s) - thiophosphate , phosphoric acid , salt (chemistry) , chemistry , ion , phosphorus , inorganic chemistry , ammonium , organic chemistry
The square arrangement of the four phosphorus atoms is the most notable structural feature of the novel cyclic thiophosphate(III) ion, which has been isolated as its ammonium salt. The anion is formed by the reaction of white phosphorus with polysulfides in organic solvents.