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Phenyl‐Substituted Dimethyleneammonium Salts: 2‐Aza‐allenium Derivatives
Author(s) -
Würthwein ErnstUlrich
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198100991
Subject(s) - nucleophile , cycloaddition , chemistry , medicinal chemistry , organic chemistry , combinatorial chemistry , catalysis
A general route to the synthetically valuable CNC compounds (1) , starts with the reaction of the substituted diamines (2) with acylium salts such as CH 3 CO + SbCl 6 − . The salts (1) take up nucleophiles and react as ene‐components in cycloaddition reactions.