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Direct Metal Exchange in Carbonylcobalt Clusters
Author(s) -
Beurich Harald,
Vahrenkamp Heinrich
Publication year - 1981
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198100981
Subject(s) - cluster (spacecraft) , metal , materials science , chemistry , crystallography , metallurgy , computer science , programming language
A convenient route to the chemistry of heterotetrahedranes is provided by exchange reactions involving CH 3 CCo 3 (CO) 9 . The chiral cluster ( 1 ) was synthesized from the aforementioned cluster by a double metal exchange; (1) crystallized spontaneously, forming optically active crystals.